GLC STUDY ON THE THERMODYNAMIC PROPERTIES OF ADDUCTION OF Ni[(C8H17O)2PS2]2 WITH KETONES

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (3): 56-59.

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GLC STUDY ON THE THERMODYNAMIC PROPERTIES OF ADDUCTION OF Ni[(C₈H₁₇O)₂PS₂]₂ WITH KETONES

Zhu Duolin¹, Yu Yunpeng¹, Ge Guoyuan¹, Xu Zeheng², You Xiaozeng²

1. Department of Chemistry, Zhen Jiang Teachers'College, Jiangsu Zhenjiang 212003;
2. Coordination Chemistry Institute, Nanjing University, Nanjing

Received:1990-03-19 Revised:1990-07-16 Published:1991-06-10 Online:1991-06-10

Abstract

Abstract: The GLC study on the thermodynamic properties of adduct formation between Ni[(C₈H₁₇O)₂PS₂]₂ and ketones was reported.The equilibrium constants at the temperatureof 333.2～363.2K were determind and can de described by the empirical equation: lgK = -1.174 - 0.6791n_c + (202.1n_c + 495.0)/T ΔH and ΔS were calculated by the least square method.It was found that -ΔH andΔS increased linearly with the number of carbon n_c in ketone molecules -ΔH = 9.48 + 3.87 n_c (kJ/mol) -ΔS = 22.5 + 13.0 n_c (J/K·mol)The nature of adduct bonds was explained by means of electro-static model.

Key words: gas-liquid chromatography, dialkydithiophosphate, ketones, thermodynamic parameter

Zhu Duolin, Yu Yunpeng, Ge Guoyuan, Xu Zeheng, You Xiaozeng. GLC STUDY ON THE THERMODYNAMIC PROPERTIES OF ADDUCTION OF Ni[(C₈H₁₇O)₂PS₂]₂ WITH KETONES[J]. Chinese Journal of Applied Chemistry, 1991, 0(3): 56-59.

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GLC STUDY ON THE THERMODYNAMIC PROPERTIES OF ADDUCTION OF Ni[(C₈H₁₇O)₂PS₂]₂ WITH KETONES

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