Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (1): 65-67.

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CYCLIZATION OF HEXENE OVER LMo(CO)5-TiCl4 CATALYST SYSTEM

Liu Hezhong, Yu Daorong, Yuan Huaxian, Hu Jeihan   

  1. Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116012
  • Received:1990-02-26 Revised:1990-07-03 Published:1991-02-10 Online:1991-02-10

Abstract: Cyclization of 1-hexene in the presence of LMo(CO)5-TiCl4 forms methylcyclopentane.A parallel relationship was found among the yield of cyclization and the isomerizationof 1-hexene and the amount of tetrahlorotitanium added.When L = PPh3, the catalyst sy-stem showed the highest cyclization activity.

Key words: hexene, cyclization, carbonyl molybdenum, titanium chloride