Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (2): 40-44.

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DYNAMIC MECHANICAL PROPERTIES OF AB CROSSLINKED POLYMERS BASED ON POLYURETHANE AND MMA

Liu Wengzhong, Lin He, Liu Jingjiang, Han Xiaozu   

  1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022
  • Received:1989-05-06 Revised:1989-08-21 Published:1990-04-10 Online:1990-04-10

Abstract: A series of AB crosslinked polymers(ABCPs)based on poly(hexamethylene adipate)-polyurethane(PHAPU)and methyl methacrylate(MMA)with various compositions were prepared by means of ultra-violet initiation polymerization. The values of crosslink density weredetermined by swelling equilibrum approach and rubberlike elasticity. The both results werein good agreement. The width of tangent δ peak at the half height was more than 60℃,andthe system was considered to be mechanically compatible.By simply varing the concentrationof the constituents, a series of damping materials, With a unique set of properties, could beobtained.

Key words: AB crosslinked polymers, polyurethanes, dynamic mechanical property, swelling equilibrium of polymer