Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (2): 30-35.

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STUDY ON FAST BOMBARDMENT MASS SPECTROMETRY (FABMS) OF LANTHANIDE CROWN ETHER COMPLEXES

Yuan Moucun1, Zhu Yufen1, Tang Dazhi1,2, Zhang Fayi1,3, Liu Shuying1   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1987-12-17 Revised:1988-09-12 Published:1989-04-10 Online:1989-04-10

Abstract: Fast atom bombardment (FAB) mass spectra of more than 10 lanthanide crown ethercomplexes were reported. A certain relationship was found between the intensities of ionsin gas phase and their reactions in solution, that was coincident with the direct sputtetingmechanism on FABMS. Therefore FABMS could be considered as a useful method to studysolution reactions. FAB, linked scanning and MIKES/CID techniques were applied in this work.

Key words: Lanthanids crown ether complex, Fast atom bombardment mass spectrometry, Metastable ion, Negative ion FABMS