Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (1): 89-90.

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ON THE VALENCE OF BARIUM IN SUPERCONDUCTING YBa2 Cu3 O~7

Zhao Liangzhong, Zhu Daoben, Zhang Jinbiao, Wang Junru, Yang Deliang, Cheng Dejun, Hu Yuxiu, Gao Kezhen, Hou Keyue   

  1. Institute of Chemistry, Academia Sinica, Beijing
  • Received:1988-04-26 Revised:1988-08-09 Published:1989-02-10 Online:1989-02-10

Abstract: XPS studies show that the valence of Ba in superconducting YBa2Cu3O~7 is + 2.Theshoulders on the Ba 3d spectrum of the air exposed superconductor did not originate fromthe chemical shift, but from the different charging effect.

Key words: X-ray pholoelectron spectroscopy(XPS), High Tc suporconductor, Barium