Chinese Journal of Applied Chemistry ›› 1987, Vol. 0 ›› Issue (3): 64-66.

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STUDY ON THE COLOUR REACTION OF BERYLLIUM WITH CHROMAZUROL B(CAB)IN THIE PRESENCE OF MIXED IONIC-NONIONIC SURFACTANTS

Yang Dingguo, Wu Yunping   

  1. Department of Textile Chemistry, North-West Institute of Textile, Xi'an
  • Received:1986-10-06 Revised:1986-12-25 Published:1987-06-10 Online:1987-06-10

Abstract: A sensitive method for trace determination of beryllium is developed. In a buffer solution of pH5.5 of (CH2)6N4-HCl and in the presence of emulsifier OP and sodium dodecylbenzene sulfonate (SDBS) Be(Ⅱ) forms a purple complex with chromazurol B(CAB). The molar absorptivity coefficient of the complex is 8.55×104(605-610nm). Beer's law is obeyed with concentration of beryllium ranging from O to 2.5μg/25ml. The composition of the complex was estimated as Be(Ⅱ):CAB=1:2. The method has been applied sactisfactority to the determination of Be in minerals.