Chinese Journal of Applied Chemistry ›› 1987, Vol. 0 ›› Issue (1): 40-43.

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OLIGOMERIZATION REACTION OF 1-BUTENE Ⅰ.CATALYTIC BEHAVIOR 0F 1, 1, 1, 5, 5, 5-HEXAFLURO-2, 4-PEN-TADIONATO-NICKEL/DIETHYL ALUMINIUM ETHOXIDE

Gao Zhanxian, Zhang Aili, Yu Jing, Zhou Keyan   

  1. Dalian Institute of Technology
  • Received:1986-03-28 Revised:1986-07-31 Published:1987-02-10 Online:1987-02-10

Abstract: In this paper, the oligomerization reaction of 1-butene has been studied using 1, 1, 1, 5, 5, 5 -haxafluro- 2, 4-pentadionato-nickel/diethyl aluminium ethoxide, (hfacac)2 Ni/Et2AlOEt, as catalyst. Results showed that (hfacac)2Ni/Et2AlOEt is an efficient catalyst for linear oligomerization of 1-butene and also cata1yzes isomerization and hydrogenation of 1-butene.