Chinese Journal of Applied Chemistry ›› 1986, Vol. 0 ›› Issue (5): 58-63.

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SYNTHESIS AND PROPERTIES OF LANTHANIDE NITRATES COMPLEXES WITH CRYPTANDS(2.2.2)AND(2.2)

Liu Shichang1, Zhu Tianpei2   

  1. 1. Dept. of Chem., Inner Mongolia Normal University, Huhehaote;
    2. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1985-05-28 Revised:1985-11-29 Published:1986-10-10 Online:1986-10-10

Abstract: Five complexes of the lanthanide nitrates with the cryptand(2.2.2) and cryptand (2.2),La(NO3)3·(2.2),Eu(NO3)3·(2.2)·H2O, Yb(NO3)3(2.2)·2H2O,La2 (NO3)6(2.2.2) MeCN·3H2O, Eu2(NO3)6·(2.2.2)·MeCN·3H2O, have been synthesized in acetonitrile.The complexes were characterized by elemental analyses, IR, NMR, DTA, TG, and electrochemical data.