Chinese Journal of Applied Chemistry ›› 1986, Vol. 0 ›› Issue (2): 74-76.

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RELATIONSHIP BETWEEN INTRINSIC VISCOSITY,DEGREE OF HYDROLYSIS OF PAM,HPAM AND ADDED SALT CONCENTRATION

Chen Jiushun1, Wang Yin2   

  1. 1. Department of Chemistry, Heilongjiang University;
    2. Heilongjiang Province Institute of Petrochemistry
  • Received:1985-02-11 Revised:1985-05-27 Published:1986-04-10 Online:1986-04-10

Abstract: Polyacrylamide (PAM) and its hydrolysed product (HPAM) were studied viscosime-trically in aqueous solution of 1, 0.5, 0, 1, 0.025 and 0.01N NaNO3. A linear relationship between tga (see Fig. 1) and degree of hydrolysis (DH%) was found with the same concentration of added salt (Cs) and the same molecular weight of poly-mers. It was also found that the intrinsic viscosity [η] of PAM and HPAM is propor-tional to the C3-1/2. The same [η] values of samples were obtained when the polymer has the same initial molecular weight, but different DH%.