Chinese Journal of Applied Chemistry ›› 1985, Vol. 0 ›› Issue (4): 31-35.
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He Binglin, Teng Kang, Sun Juntan, Li Hong
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Abstract: Synthesized H4Ru4 (CO)12 and H4Ru4(CO)10(PPh3)2 in this laboratory were anchored on the modified polymer supports: P-Ph-CH2PPh2, SiO2 Ph-CH2PPh2, P-Ph-CH2N(Et)P(NEt2)2. They were used as catalysts for the hydrogenation and isomerization of 1-hexene. The effects of the reaction conditions, i.e.variety of solvents, reaction time,crosslinking density of the organic supports,the polymer ligands used and the ligand/metal ratio of the catalysts on the catalytic properties of the cluster were investigated.
He Binglin, Teng Kang, Sun Juntan, Li Hong. PREPARATION AND CATALYTIC PROPERTIES OF POLYMER-BOUND TETRARUTHENIUM CLUSTER:DODECACARBONYLTETRAHYDROTETRARUTHENIUM[J]. Chinese Journal of Applied Chemistry, 1985, 0(4): 31-35.
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