中华医学超声杂志

应用化学 ›› 2018, Vol. 35 ›› Issue (10): 1271-1276.DOI: 10.11944/j.issn.1000-0518.2018.10.170386

• 研究论文 • 上一篇    

香豆素类铝离子荧光化学传感器的合成及性能

杨文生(),杨菀,慕建英,马亚军   

  1. 榆林学院化学与化工学院 陕西 榆林 719000
  • 收稿日期:2017-10-27 接受日期:2018-02-26 出版日期:2018-10-01 发布日期:2018-10-09
  • 通讯作者: 杨文生
  • 基金资助:
    国家自然科学基金(21763030)榆林学院博士科研启动基金(16GK14)资助项目

Synthesis and Characterization of Coumarin Based Aluminum Ion Fluorescence Chemosensor

YANG Wensheng(),YANG Wan,MU Jianying,MA Yajun   

  1. School of Chemistry and Chemical Engineering,Yulin University,Yulin,Shaanxi 719000,China
  • Received:2017-10-27 Accepted:2018-02-26 Published:2018-10-01 Online:2018-10-09
  • Contact: YANG Wensheng
  • Supported by:
    Sopported by the National Natural Science Foundation of China(No.21763030), the Dr Scientific Research Start-Up Foundation of Yulin College(No.16GK14)

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摘要：

为了方便快捷地检测铝离子,本文以7-羟基香豆素为原料合成了铝离子荧光化学传感器。 通过质谱、核磁共振谱、紫外可见分光光度计等技术手段研究了传感器的结构和性能。 结果表明,该传感器对铝离子有很好的选择性,其检出限为8.5×10-8 mol/L,其识别过程具有可逆性,同时,Job's plot曲线表明二者形成配位比为1:1的稳定配合物。 该研究对生物体及环境领域中铝离子的实时监测具有潜在的应用价值。

关键词: 香豆素, 荧光化学传感器, 铝离子

Abstract:

For the sake of convenient and quick detection of aluminum ion, an aluminum ion fluorescent chemosensor was synthesized from 7-hydroxyl coumarin. Its structure was verified by mass spectrometry and nuclear magnetic resonance spectrum. The properties and structure of fluorescence chemosensor were characterized by mass spectrometry(MS), nuclear magnetic resonance spectroscopy(NMR), UV-vsisible absorption spectrum(UV-Vis). The results reveal that the sensor has good selectivity toward aluminum ion. The limit of detection is 8.5×10-8 mol/L, and the identification process is reversible. The Job's plot indicates that the sensor and aluminum ion forms stable complex in 1:1 ratio. Therefore, this fluorescent chemosensor has potential in real time monitoring aluminum ion in biological and environmental applications.

Key words: coumarin, fluorescence chemosensor, aluminum ion

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