聚二苯基乙炔耐溶剂纳滤膜的制备与性能

doi:10.11944/j.issn.1000-0518.2017.04.160297

摘要/Abstract

摘要：

聚二苯基乙炔(PDPA)不溶于有机溶剂,是理想的新型耐溶剂纳滤膜材料。采用溶液浇铸法制备聚[1-(4-三甲基硅基)苯基-2-苯乙炔](PTMSDPA)均质膜,经脱硅反应得到PDPA膜,研究其乙醇渗透性能和染料截留性能。结果表明,乙醇渗透通量与压力呈正相关性,传质机理可能介于孔流机理和溶解扩散机理之间的过渡区。染料的分子尺寸、电荷性质以及染料和膜之间的相互作用共同影响PDPA膜的截留性能。

关键词: 聚二苯基乙炔, 耐溶剂纳滤, 染料截留

Abstract:

Poly(diphenylacetylene)(PDPA) is insoluble in organic solvents which makes it a new type promising membrane material for solvent resistant nanofiltration. PDPA membranes were obtained by desilylation of poly[1-phenyl-2-[p-(trimethylsilyl)phenyl]acetylene](PTMSDPA) dense membranes, which were prepared by solution-casting method. The permeation of pure ethanol and the retention of dye/ethanol solutions were investigated. The ethanol permeability of the PDPA membrane increases linearly with increased applying pressure. The transport mechanism for solvents in PDPA membrane can fall in the transition range between a pore flow and a solution diffusion mechanism. Moreover, the dye retention of the PDPA membrane is controlled by the molecular size of the dyes, the charge character and interaction between the dyes and the membrane.

Key words: poly(diphenylacetylene), solvent resistant nanofiltration, dye retention

张颖, 胡雁鸣, 李战胜, 许洁, 夏玉萍, 增田俊夫. 聚二苯基乙炔耐溶剂纳滤膜的制备与性能[J]. 应用化学, 2017, 34(4): 443-448.

ZHANG Ying, HU Yanming, LI Zhansheng, XU Jie, XIA Yuping, MASUDA Toshio. Preparation and Performance of Solvent Resistance Poly(diphenylacetylene) Nanofiltration Membranes[J]. Chinese Journal of Applied Chemistry, 2017, 34(4): 443-448.

参考文献

[1]	Marchetti P F M,Solomon J,et al. Molecular Separation with Organic Solvent Nanofiltration:A Ccritical Review[J]. Chem Rev,2014,114(21):10735-10806.
[2]	Cheng X,Zhang Y,Wang Z,et al.Recent Advances in Polymeric Solvent-resistant Nanofiltration Membranes[J]. Adv Polym Technol,2014,33(S1):21455.
[3]	Vandezande P,Gevers L E M,Vankelecom I F J. Solvent Resistant Nanofiltration:Separating on a Molecular Level[J]. Chem Soc Rev,2008,37(2):365-405.
[4]	WEI Wang XIANGLI Fenjuan,JIN Wanqin,et al. Solvent Resistant Nanofiltration Membranes[J]. Prog Chem,2007,19(10):1592-1597(in Chinese). 卫旺,相里粉娟,金万勤,等. 耐溶剂纳滤膜[J]. 化学进展,2007,19(10):1592-1597.
[5]	PAN Cheng,WANG Yu,LI Xuemei,et al.The Preparation and Application of PES Hollow Fiber Nanofiltration Membrane by Coating Method[J]. Membr Sci Technol,2012,32(1):18-22(in Chinese). 潘成,王雨,李雪梅,等. 涂层法制备聚醚砜中空纤维纳滤膜及应用[J]. 膜科学与技术,2012,32(1):18-22.
[6]	XING Yanan,SU Baowei,ZHEN Hongyan.Research Progress of Solvent Resistant Nanofiltration Membranes[J]. Chem Ind Eng Prog,2015,34(11):3832-3840(in Chinese). 邢雅南,苏保卫,甄宏艳. 耐溶剂纳滤膜的制备与应用研究进展[J]. 化工进展,2015,34(11):3832-3840.
[7]	Fritsch D,Merten P,Heinrich K,et al. High Performance Organic Solvent Nanofiltration Membranes:Development and Thorough Testing of Thin Film Composite Membranes Made of Polymers of Intrinsic Microporosity(PIMs)[J]. J Membr Sci,2012,401/402:222-231.
[8]	Volkova A V,Stamatialis D F,Khotimsky V S,et al.Poly[1-(trimethylsilyl)-1-propyne] as a Solvent Resistance Nanofiltration Membrane Material[J]. J Membr Sci,2006,281(1/2):351-357.
[9]	Volkov A V,Parashchuk V V,Stamatialis D F,et al.High Permeable PTMSP/PAN Composite Membranes for Solvent Nanofiltration[J]. J Membr Sci,2009,333(1/2):88-93.
[10]	Volkov A,Yushkin A,Grekhov A,et al.Liquid Permeation Through PTMSP:One Polymer for Two Different Membrane Applications[J]. J Membr Sci,2013,440:98-107.
[11]	XU Jie,ZHANG Ying,LI Zhansheng,et al.Nanofiltration Performance Research of PTMSDPA Membrane[J]. Membr Sci Technol,2016,36(1):50-54(in Chinese). 许洁,张颖,李战胜,等. PTMSDPA纳滤膜的渗透性能研究[J]. 膜科学与技术,2016,36(1):50-54.
[12]	Raharjo R D,Lee H J,Freeman B D,et al.Pure Gas and Vapor Permeation Properties of Poly[1-phenyl-2-[p-(trimethylsilyl)phenyl]acetylene](PTMSDPA) and Its Desilylated Analog, Poly[diphenylacetylene](PDPA)[J]. Polymer,2005,46(17):6316-6324.
[13]	Hu Y,Sakaguchi T,Shiotsuki M,et al.Synthesis and Properties of Poly(diphenylacetylenes) Containing Siloxy and Halogen/Methyl Groups and Their Desilylated Membranes[J]. Polymer,2007,48(1):43-49.
[14]	HUA Youqing,JIN Riguang.Polymer Physics[M]. Beijing:Chemical Industry Press,2013(in Chinese). 华幼卿,金日光. 高分子物理[M]. 北京:化学工业出版社,2013.
[15]	CHENG Nenglin. Solvents Handbook.4th Ed[M]. Beijing:Chemical Industry Press,2008(in Chinese). 程能林. 溶剂手册[M]. 第4版. 北京:北京工业出版社,2008.
[16]	Machado D R,Hasson D,Semiat R.Effect of Solvent Properties on Permeate Flow Through Nanofiltration Membranes. Part I:Investigation of Parameters Affecting Solvent Flux[J]. J Membr Sci,1999,163(1):93-102.
[17]	Uragami T,YonoT,Sugihara M. Studies on Syntheses and Permeabilities of Special Polymer Membranes. XX.Permeabilities of Alcohols and Hydrocarbons Through Acrylonitrile-butadiene-styrene Terpolymer Membranes[J]. Angew Makromol Chem,1979,82(1):89-102.
[18]	Wijmans J G,Baker R W.The Solution-Diffusion Model:A Review[J]. J Membr Sci,1995,107:1-21.
[19]	Tsar'Kov S E,Malakhov A O,Litvinova E G,et al. Nanofiltration of Dye Solutions Through Membranes Based on Poly(trimethylsilylpropyne)[J]. Pet Chem,2013,53(7):537-545.
[20]	Tsarkov S,Khotimskiy V,Budd P M,et al. Solvent Nanofiltration Through High Permeability Glassy Polymers:Effect of Polymer and Solute Nature[J]. J Membr Sci,2012,423/424:65-72.