苯氯乙酮焚烧销毁机理及作业参数优化

doi:10.3724/SP.J.1095.2012.00375

摘要/Abstract

摘要： 根据燃烧理论和苯氯乙酮的化学结构，分析了焚烧法销毁苯氯乙酮的反应机理和影响焚烧销毁效果的主要因素，确定了苯氯乙酮完全燃烧的反应产物与反应方程式。通过焚烧实验研究了一燃室和二燃室温度、单次进料量、进料时间间隔对苯氯乙酮焚烧销毁效果的影响，据此优化确定了利用特种危险化学品焚烧销毁装置焚烧销毁苯氯乙酮的主要作业参数。结果表明，在过剩空气系数为2.5、单次进料量400 g、一燃室温度800 ℃、二燃室温度1200 ℃、进料时间间隔3 min的条件下，利用实验设备能科学有效焚烧销毁苯氯乙酮。

关键词: 危险化学品, 催泪剂, 苯氯乙酮, 焚烧, 销毁, 参数优化

Abstract: According to combustion theory and chemical structure of chloroacetophenone, the principle for destroying chloroacetophenone by incineration was analyzed, and the reaction products and equation of the incineration were determined. By incineration experiments, the major influencing factors, such as feed-in waste quantity, feed-in time interval, temperatures of the first and second fireboxes, were discussed. Moreover, the optimized parameters for destroying chloroacetophenone by incineration equipment were determined. As a result, chloroacetophenone may be scientifically and thoroughly destroyed by the special incineration equipment under the following optimized parameters:the excess air coefficient is 2.5, the feed-in waste quantity is 400 g each time, the feed-in time interval is 3 min, the temperature of the first firebox is 800 ℃, while the second firebox is 1200 ℃.

Key words: danger chemicals, lacrimatory agent, chloroacetophenone, incineration, destruction, optimized paramete

中图分类号:

O643.2

王玄玉, 诸雪征, 王黎娜. 苯氯乙酮焚烧销毁机理及作业参数优化[J]. 应用化学, DOI: 10.3724/SP.J.1095.2012.00375.

WANG Xuanyu*, ZHU Xuezheng, WANG Lina. Principle and Optimized Parameters for Destroying Chloroacetophenone by Incineration Equipment[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2012.00375.

苯氯乙酮焚烧销毁机理及作业参数优化

Principle and Optimized Parameters for Destroying Chloroacetophenone by Incineration Equipment

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