中华医学超声杂志

应用化学 ›› 1998, Vol. 0 ›› Issue (2): 48-51.

• 研究论文 • 上一篇    下一篇

离子交换树脂负载Ni-B无定形合金催化剂的制备与性能

贺岩峰, 关毅, 廖巧丽, 秦永宁   

  1. 天津大学化工系 天津300072
  • 收稿日期:1997-06-26 修回日期:1997-09-09 出版日期:1998-04-10 发布日期:1998-04-10

Preparation and Catalytic Property of Ion-exchange Resin Supported Amorphous Ni-B Alloy Catalysts

He Yanfeng, Guan Yi, Liao Qiaoli, Qin Yongning   

  1. Department of Chemical Engineering, Tianjin University, Tianjin 300072
  • Received:1997-06-26 Revised:1997-09-09 Published:1998-04-10 Online:1998-04-10

PDF

479

被引次数

18 | 3

摘要： 制备了一种新型离子交换树脂负载的Ni-B无定形合金催化剂。用3种树脂作为催化剂载体,即弱酸型阳离子树脂D152,强酸型阳离子树脂D72及强碱型阴离子树脂D261.用XPS、TEM和ICP等技术对催化剂进行了表征。结果表明,催化剂上镍与带有功能基的载体树脂之间有着很强的相互作用,但其强度与所带的功能基有关。3种催化剂Ni2p3/2的XPS谱图上,NiB/D152催化剂的氧化态峰最小,而NiB/D261的氧化态峰最大。异丙醇脱氢反应活性实验证实了这一结果。

关键词: 离子交换树脂, Ni-B无定形合金催化剂, 异丙醇脱氢

Abstract: A novel ion-exchange resin supported amorphous Ni-B alloy catalyst was prepared. Three kinds of resins were used as supporter: weakly acidic cation exchanger D152, strong acidic cation exchanger D72 and strong basic anion exchanger D261. XPS, TEM and ICP were used to characterize the catalysts. The results showed that the nickel on the catalysts has a strong interaction with the support resins and the interaction varies with the functional group of the resin. Catalyst Ni-B/D261 gave the most oxide peak of Ni 2p3/2 level in XPS spectrum and catalyst Ni-B/D152 the least. The activity experiments of the liquid phase dehydrogenation of 2-propanol confirmed the results.

Key words: ion-exchange resin suported catalyst, amorphous Ni-B alloy catalyst, propanol dehydrogenation

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