应用化学 ›› 1997, Vol. 0 ›› Issue (2): 110-112.

• 研究论文 • 上一篇    下一篇

无极磁粉的制备 1.亚铁盐空气氧化直接合成纺锤形α-Fe2O3

魏雨, 刘晓林, 郑学忠   

  1. 河北师范大学化学系, 石家庄 050016
  • 收稿日期:1996-07-26 修回日期:1996-11-06 出版日期:1997-04-10 发布日期:1997-04-10

Preparation of Non-polar Magnetic Powder 1.Direct Synthesis of Spindle α-Fe2O3 from FeSO4 by Air Oxidation

Wei Yu, Liu Xiaolin, Zheng Xuezhong   

  1. Department of Chemistry, Hebei Normal University, Shijiazhuang 050016
  • Received:1996-07-26 Revised:1996-11-06 Published:1997-04-10 Online:1997-04-10

摘要: 无极(Non-polar)磁粉 γ-Fe2O3 由于在高密度记录、高保真及温度稳定好等方面有着卓越的性能, 如内部不产生磁极、表面光滑及分散性好. 不但适用于平行记录, 也适合于垂直记录[ 1], 是一种理想的磁记录材料。

关键词: 纺锤形α-Fe2O3, 空气氧化法, Fe(OH)2

Abstract: γ-FeOOH crystals were grown from FeSO4 by the air oxidation of ferrous hydroxide suspension in the presence of EDTA, and then 100% spindle α-Fe2O3 particles were prepared by adding 0.0025 mol/L hydroxyethylidene diphosphonic acid(HEDP)at 90~95℃. The mean particle length is 150~180 nm and the axial ratio is 3.5~3.8. A series of experiments were carried out with HEDP concentrations ranging from 0.0015 to 0.003 mol/L. The effect of HEDP concentration on α-Fe2O3 morphology is discussed.

Key words: spindel α-Fe2O3, air oxidation, Fe(OH)2