应用化学 ›› 1997, Vol. 0 ›› Issue (2): 13-15.

• 研究论文 • 上一篇    下一篇

甘油单醚类化合物对纤维素膜的增塑作用

肖超渤, 张曦, 张俐娜   

  1. 武汉大学化学系, 武汉 430072
  • 收稿日期:1996-08-09 修回日期:1996-11-27 出版日期:1997-04-10 发布日期:1997-04-10

The Plasticization Effect of Glycerin Monoethers on Regenerated Cellulose Film

Xiao Chaobo, Zhang Xi, Zhang Lina   

  1. Department of Chemistry, Wuhan University, Wuhan 430072
  • Received:1996-08-09 Revised:1996-11-27 Published:1997-04-10 Online:1997-04-10

摘要: 报道甘油单丁醚、单己醚、单庚醚和单辛醚4种化合物的合成,并用作再生纤维素膜的增塑剂。实验结果表明这4种甘油单醚类化合物对纤维素膜具有较好的增塑作用,随增塑剂单醚碳原子数的增加,增塑效果降低,但增塑剂与纤维素分子间相互作用增强。经甘油单己醚、单庚醚和单辛醚增塑的再生纤维素膜其耐水洗性明显高于甘油增塑的膜。

关键词: 再生纤维素膜, 甘油单醚, 增塑剂

Abstract: Glycerin α-monobutyl ether, α-monohexyl ether, α-monoheptyl ether and α-monooctyl ether were synthesized and used as the plasticizers of regenerated cellulose films. The structure and properties of plasticized films were studied by FT IR, DTA and mechanical strength measurement. Experimental results showed that these four glycerin α-monoethers had good plasticization effects on the films. With increasing number of carbon atoms of etheric moiety, the interaction between molecules of plasticizer and cellulose increased and plasticization effects decreased. The resistance against water washing of regenerated cellulose films plasticized by glycerin α-monohexyl ether, α-monoheptyl ether and α-monoctyl ether was obviously higher than that of the films plasticized by glycerin.

Key words: regenerated cellulose film, glycerin α-monoether, plasticizer