应用化学 ›› 1996, Vol. 0 ›› Issue (6): 39-41.

• 研究论文 • 上一篇    下一篇

聚氧乙烯-高氯酸锂配合物电致变色光窗的研究

崔敏慧1, 吴正华2, 邱思畴2, 谢洪泉3   

  1. 1. 南京大学化学化工学院 南京 210093;
    2. 华中理工大学固体电子学系 武汉;
    3. 华中理工大学化学系 武汉
  • 收稿日期:1996-02-07 修回日期:1996-06-17 出版日期:1996-12-10 发布日期:1996-12-10

Electrochromic Window Based on Polyoxyethylene-Lithium Perchlorate Complex

Cui Minhui1, Wu Zhenghua2, Qiu Sichou2, Xie Hongquan3   

  1. 1. Department of Chemistry, Nanjing University, Nanjing 210093;
    2. Department of Solid State Electronics, Huazhong University of Science and Technology, Wuhan;
    3. Department of Chemistry, Huazhong University of Science and Technology, Wuhan
  • Received:1996-02-07 Revised:1996-06-17 Published:1996-12-10 Online:1996-12-10

摘要: 以WO3为电致变色层、NiOx4,配合物为电解质制备了全固态电致变色光窗。电色窗在700~900 nm之间的调制深度超过50%.电色窗的电色能力随温度的升高及LiClO4盐浓度的增大而加强,并且电色窗具有较好的信息贮存能力。

关键词: 聚氧乙烯, 高氯酸锂, 电致变色光窗

Abstract: A novel ausolid-state electrochromic window was prepared by using WO3 as electrochromic layer,NiOx as counter-electrode layer and oxymethylene-linked polyoxyethylene/LiClO4 complex with good transparency as electrolyte.The modulation depth from 700 nm to 900 nm can exceed 50% The electrochromic ability of the window increases with increasing temperature and increasing LiClO4 concentration,and the window exhibits good storage life of information without energy supply.

Key words: polyoxyethylene, lithium perchlorate, electrochromic window