应用化学 ›› 1995, Vol. 0 ›› Issue (4): 21-26.

• 研究论文 • 上一篇    下一篇

铅在铂电极上的还原电位溶出分析法

张亚利1, 焦奎2, 刘澄凡2, 刘海燕2   

  1. 1. 青岛大学工商学院应用化学系, 青岛;
    2. 青岛化工学院应用化学系, 青岛 266042
  • 收稿日期:1994-09-21 修回日期:1995-03-06 出版日期:1995-08-10 发布日期:1995-08-10
  • 基金资助:
    中国科学院长春应用化学研究所电分析开放实验研究室基金资助课题

Reductive Stripping Potentiometry of Lead on Platinum Electrode

Zhang Yali1, Jiao Kui2, Liu Chengfan2, Liu Haiyan2   

  1. 1. Department of Applied Chemistry, College of Engineering and Commerce, Qingeao University, Qingdao;
    2. Department of Applied Chemistry, Qingdao institute of Chemical Technology, Qingdao 266042
  • Received:1994-09-21 Revised:1995-03-06 Published:1995-08-10 Online:1995-08-10

摘要: 研究了以亚铁氰化钾为还原剂铅在铂电极上的还原电位溶出法;讨论了电极的预处理、阳极富集和随后的还原电位溶出及铅测定的干扰.

关键词: 铅, 还原电位溶出, 亚铁氰化钾, 铂电极

Abstract: The reductive stripping potentiometric analysis of lead in the presence of potassi-um ferrocyanide as reducing agent on platinum electrode has been investigated. The pretreat-ment of the electrode, processes of anodic preconcentration and subsquent analysis,and theinterference of foreign ions were discussed.The linear range was 1? 10-7 to 5 ? 10-6mol/L for lead.

Key words: lead, redtictive stripping potentiometry, potassium ferrocyanide, platinum elec-trode