中华医学超声杂志

应用化学 ›› 1995, Vol. 0 ›› Issue (2): 37-41.

• 研究论文 • 上一篇    下一篇

多二茂铁基二氮杂己烷及其过渡金属配合物的合成

边占喜, 王健春, 李逢泽   

  1. 内蒙古大学化学系, 呼和浩特 010021
  • 收稿日期:1994-09-15 修回日期:1994-12-05 出版日期:1995-04-10 发布日期:1995-04-10

Synthesis of Multiferrocenyl Diazahexanes and Transition Metal Complexes

Bian Zhanxi, Wang Jianchun, Li Fengze   

  1. Department of Chemistry, Inner Mogolia University, Hohhot 010021
  • Received:1994-09-15 Revised:1994-12-05 Published:1995-04-10 Online:1995-04-10

PDF

660

被引次数

44 | 19

摘要： 乙二胺与二茂铁甲醛或双二茂铁甲基氟硼酸盐反应,合成了1,6-二(二茂铁基)-2,5-二氮杂已烷和1,1,6,6-四(二茂铁基)-2,5-二氮杂已烷.它们与过渡金属(Fe2+、Co2+、Ni2+、Cu2+、Zn2+)盐在乙醇或乙醇-二氯甲烷中反应,制得14种过渡金属配合物.对这些化合物进行了表征.二种配体及其铜配合物用作复合固体推进剂的燃速调节剂时,基本不迁移,而燃速催化效率均超过辛基二茂铁.

关键词: 二(二茂铁基)-二氮杂己烷, 四(二茂铁基)-二氮杂己烷, 过渡金属配合物, 燃速调节剂

Abstract: Two ligands 1,6-diferrocenyl-2,5-diazahexane and 1,1,6,6-tetraferrocenyl-2,5-diazahexane,were synthesized by reacting ethylene diamine with ferrocenyl formaldehydeand biferrocenylmethyl flouroborate respectively. Fourteen complexes of the ligands with Fe2+,Co2+,Ni2+,Cu2+ and Zn2+ were prepared. All the compounds have been characterized by elemental analysis, DTA and IR,1H NMR measurements. The ligands and their cuprouscomplex have been used as burning-rate modifiers for composite solid propellants. No migration was found in composite propellants. The catalytic efficiency of burning-rate was over that of octylferrocene.

Key words: diferrocenyl diazahexane, tetraferrocenyl diazahexane, transition metal complex, burning-rate modifier

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