应用化学 ›› 1995, Vol. 0 ›› Issue (1): 111-113.

• 研究论文 • 上一篇    下一篇

固态缩聚尼龙66的熔化行为

沈百拴, 张喜亮, 李新法   

  1. 郑州大学材料工程系, 郑州 450052
  • 收稿日期:1994-01-10 修回日期:1994-06-18 出版日期:1995-02-10 发布日期:1995-02-10

The Melting Behavior of Polyamide66 Prepared by Solid State Polycondensation

Shen Baishuan, Zhang Xiliang, Li Xinfa   

  1. Department of Materials Engineering, Zhengzhou University, Zhengzhou 450052
  • Received:1994-01-10 Revised:1994-06-18 Published:1995-02-10 Online:1995-02-10

摘要: 关于固态缩聚反应的研究国内外已有报道.但未见固态缩聚尼龙66(SSPPA66)熔化行为的报道.本文用DSC方法研究了固态缩聚尼龙66的熔化行为,分析其产生熔融双峰的原因.

关键词: 尼龙66, 固态缩聚物, 熔化行为, 差示扫描量热注

Abstract: By using DSC techniques,the melting behvior of nascent polyamide-66 preparedby solid state polycondensation (SSPPA66) and SSPPA66 film casted from formic acid solution has been investigated. A single melting peak for nascent SSPPA66 and double meltingpeaks for SSPPA66 film were observed.It appeared that in the SSPPA66 film there are twokinds of crystal with different crystalline structure.

Key words: nylon66, solid state polycondensate, melting behvior, differential:canning calo-rimetry