应用化学 ›› 1992, Vol. 0 ›› Issue (1): 47-50.

• 研究论文 • 上一篇    下一篇

无亲水基团取代的四苯基卟吩类LB膜的制备与表征

王文韵1, 崔海宁1, 周恩乐1, 赵晓光1, 王新平1, 羊彦衡1, 于宝贵2, 关中素2   

  1. 1. 中国科学院长春应用化学研究所, 长春 130022;
    2. 中国科学院长春物理研究所
  • 收稿日期:1990-11-21 修回日期:1991-01-26 出版日期:1992-02-10 发布日期:1992-02-10

LANGMUIR-BLODGETT FILMS OF TETRAPHENYLPORPHIN DERIVATIVES WITHOUT HYDROPHILIC SUBSTITUENTS

Wang Wenyun1, Cui Haining1, Zhou Enle1, Zhao Xiaoguang1, Wang Xinping1, Yang Yanheng1, Yu Baogui2, Guan Zhongsu2   

  1. 1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 13002;
    2. Changchun Institute of Physics, Academia Sinica, Changchun
  • Received:1990-11-21 Revised:1991-01-26 Published:1992-02-10 Online:1992-02-10

摘要: 拉制了4种无亲水基团的四苯基卟吩LB膜,用透射电镜、荧光寿命、荧光光谱和紫外-可见光谱测量表征了膜的形貌和结构,发现膜中卟吩主要以聚集体形式存在。

关键词: 四苯基卟吩衍生物, LB膜, 形貌结构

Abstract: LB films of tetraphenylporphin derivatives without hydrophilic substituents have been prepared. The morphorlogy and structure of these films were characterized by transmission electron microscopy, fluorescence lifetime, fluorescence spectra and UV-Vis spectra. It is found that these porphins mainly form aggregates in the ordered films.

Key words: LB film, tetraphenylporphin derivative, morphorlogical structure