中华医学超声杂志

应用化学 ›› 1991, Vol. 0 ›› Issue (5): 77-80.

• 研究简报 • 上一篇    下一篇

固相配位化学反应研究 ⅩⅩⅩⅦ XRD法研究Cu(Ac)2·H2O与甘氨酸的室温固相配位化学反应

成全, 贾殿赠, 缪强, 忻新泉   

  1. 南京大学配位化学研究所, 南京 210008
  • 收稿日期:1990-10-30 修回日期:1991-01-18 出版日期:1991-10-10 发布日期:1991-10-10
  • 基金资助:
    国家自然科学基金;国家教委博土点基金

STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDSⅩⅩⅩⅦ.XRD STUDY OF SOLID STATE REACTION BETWEEN Cu(Ac)2·H2O AND GLYCINE

Cheng Quan, Jia Dianzeng, Miao Qiang, Xin Xinquan   

  1. Institute of Coordination Chemistry, Nanjing University, Nanjing 210008
  • Received:1990-10-30 Revised:1991-01-18 Published:1991-10-10 Online:1991-10-10

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摘要： 固相配位化学研究配位化合物在固态条件下的反应及性质。有关室温条件下的固相配位反应的报导很少[1]。本文用XRD方法研究Cu(Ac)2·H2O与甘氨酸在室温条件下的固相配位化学反应,探讨碱对反应产物的影响。

关键词: 醋酸铜, 甘氨酸, 固相反应, 配位化合物, 异构化

Abstract: Solid state reaction between Cu(Ac)2·H2O and glycine has been investigated by XRDmethod.The reaction product was cis-[Cu(gly)2)·H2O and trans-[Cu(gly)2]·H2O dependingon the presence of solid alkali.Water, whether it is coordinated, in crystalline or as a mo-isture in alkali shows an obvious effect on the solid state reaction.

Key words: Copper acctate, glycine, solid state reaction, complex, isomerization

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