应用化学 ›› 1991, Vol. 0 ›› Issue (4): 67-70.
• 研究简报 • 上一篇 下一篇
王清民, 师同顺, 代友红, 曹锡章
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Wang Qingmin, Shi Tongshun, Dai Youhong, Cao Xizhang
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摘要： 实验表明,Mn(Ⅲ)卟啉对理解血红蛋白的催化反应很有意义[1]。Mn(Ⅲ)卟啉突出的性质是配位还原性,尤其与有机碱的反应。Карманова等研究了四苯基卟啉锰(Ⅲ)(TPPMn(Ⅲ)Cl)与有机碱的配位还原反应。
关键词: 光原锰(Ⅲ)卟啉二甲酯, 有机碱, 配位还原反应
Abstract: The title compound was extracted and synthesized from pig blood.Its coordination reduc-tion reactions with organic bases have been studied using spectral technique.The factorsaffecting the activity of coordination reduction were examined in comparison with otherporphyrin manganese (Ⅲ).The results demostrate that (a) the porphyrin ring with strongelectron-attracting groups is favor of the coordination reduction, (b) the namber of organicbase molecules participated in reaction depends on the structure of porphyrin, (c) orgapicbases studied gave the following reducing power: piperidine, n-propylamine>pyridine>imi-dazole.
Key words: Photodimethylesterprotoporphyrin manganese(Ⅲ)chloride, piperidine, n-propylamine, pyridine, imidazole
王清民, 师同顺, 代友红, 曹锡章. 光原锰(Ⅲ)卟啉二甲酯与有机碱配位还原反应研究[J]. 应用化学, 1991, 0(4): 67-70.
Wang Qingmin, Shi Tongshun, Dai Youhong, Cao Xizhang. COORDINATION REDUCTION OF PHOTODIMETHYLESTER-PROTOPORPHYRIN MANGANESE(Ⅲ)CHLORIDE BY ORGANIC BASES[J]. Chinese Journal of Applied Chemistry, 1991, 0(4): 67-70.
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