应用化学 ›› 1990, Vol. 0 ›› Issue (2): 6-9.

• 研究论文 • 上一篇    下一篇

Mn(PMBP)2加合物的合成和波谱研究

诸葛卸梅, 陈克, 陈焱, 冯亚菲, 陈继敏, 徐元植   

  1. 浙江大学化学系 杭州 310027
  • 收稿日期:1989-03-18 修回日期:1989-05-27 出版日期:1990-04-10 发布日期:1990-04-10

SYNTHESIS AND SPECTRAL STUDIES OF Mn(PMBP)2 ADDUCTS

Zhuge Xiemei, Chen Ke, Chen Yan, Feng Yafei, Chen Jimin, Xu Yuanzhi   

  1. Department of Chemistry, Zhejiang University, Hangzhou 310027
  • Received:1989-03-18 Revised:1989-05-27 Published:1990-04-10 Online:1990-04-10

摘要: 本文合成了Mn(PMBP)2与乙醇,β-甲基吡啶,γ-甲基吡啶,以及乙二胺的加合物。通过元素分析,摩尔电导、磁化率测定。电子光谱。红外光谱及顺磁共振波谱等对加合物进行了系统的表征。

关键词: 锰(Ⅱ), 1-苯基-3-甲基-4-苯甲酰吡啶酮-5, 加合物, 电子顺磁共振

Abstract: The adducts of Mn(PMBP)2(PMBP=1-phenyl-3-methyl-4-benzoyl-pyrazolone-5)withethanol, 3-methylpyridine, 4-methylpyridine and ethyienediamine have been synthesized andcharacterized by elemental analysis, molai conductance, magnetic susceptibility, UV IR and EPR spectra measurements.

Key words: manganese(Ⅱ), 1-phenyl-3-methyl-4-benzoyl-pyrazo-lone-5, adduct, electron paramagnetic resonance