π-烯丙基碘化铁含氮配合物的合成

摘要/Abstract

摘要： π-烯丙基卤化铁含氮配位体的络合结构被认为是铁体系催化丁二烯聚合反应的活性中心^[1,2],所以合成具有这种结构的模型化合物并研究其催化活性是很有意义的。

关键词: π-烯丙基碘化铁含氮配合物, π-烯丙基碘化铁三羰基配合物, 配位体交换反应

Abstract: In this work usin g ligands exchange reaction between η³-allylirontricarbonyl iodideand α,α′-dipyridyl or phenanthrolire, two new and catalytically active nitrogenous comp-lexes of η³-allyliron halide, η³-C₃H₅FeI(CO) dipy and η³-C₃H₅ FeI(CO)phen,were synthesi-zed successfully.Their chemical structures were characterized by elemental analysis, GCand IR.

Key words: Nitrogenous complex of η³-allyliron iodide, η³-Allylirontricarbonyl iodide, Ligands exchange

刘静芝, 高红玉, 马德清, 黄景琴, 刘国智. π-烯丙基碘化铁含氮配合物的合成[J]. 应用化学, 1989, 0(5): 56-58.

Liu Jingzhi, Gao Hongyu, Ma Deqing, Huang Jingqin, Liu Guozhi. SYNTHESIS OF NITROGENOUS COMPLEXES OF η³-ALLYLIRON IODIDE[J]. Chinese Journal of Applied Chemistry, 1989, 0(5): 56-58.