应用化学 ›› 1987, Vol. 0 ›› Issue (4): 26-30.

• 研究论文 • 上一篇    下一篇

对影响光散射强度分布的几种因素的探讨——Ⅰ.截断效应及内部无序性对散射光强分布曲线线形的影响

杨秉新, 王长胜, 孙春荣, 刘立志   

  1. 中国科学院长春应用化学研究所
  • 收稿日期:1985-12-16 修回日期:1986-07-07 出版日期:1987-08-10 发布日期:1987-08-10

STUDIES OF SCATTERING INTENSITY DISTRIBUTION Ⅰ.EFFECTS OF TRUNCATION AND INTERNAL DISORDER OF SPHERLITES ON PROFILE OF SALS CURVES

Yang Bingxin, Wang Changshen, Sun Chunrong, Liu Lizhi   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1985-12-16 Revised:1986-07-07 Published:1987-08-10 Online:1987-08-10

摘要: 本工作从实验上考察了球晶截断效应及内部无序性对聚乙烯光散射强度分布曲线线形的影响,并同用二维截断球模型计算出的结果进行了比较,表明截断效应及内部无序性均可使散射光强度分布曲线漫宽,其程度随这些参数的增加而增加;截断效应主要影响小角度区域的散射光强,内部无序性则对大角度区域有较大的影响,二者相比内部无序性的影响似平起主要作用。所得结果与文献报导一致。

Abstract: Scattering intensity distributions from polyethylene and irradiated polyethylene were experimentally studied by small angle light scattering method and compared with those calculated on two-dimensional truncated spherulite model. The results indicated that both the truncation effect and internal disorder might widen the profile of scattering intensity distribtion curves. The degree of widening increases with the truncation and disorder. The truncation results in the increase of the scattering intensity jn the small angle region while the internal disorder shows influence on the wide angle region. It seems that the internal disorder has much more effect than truncation. The results agree well with that reported in literature.