应用化学 ›› 1987, Vol. 0 ›› Issue (4): 6-11.

• 研究论文 • 上一篇    下一篇

交流示波极谱基础研究——Ⅰ.底液示波极谱曲线的端点电位理论

毕树平, 马新生, 高鸿   

  1. 南京大学化学系
  • 收稿日期:1986-08-25 修回日期:1987-02-21 出版日期:1987-08-10 发布日期:1987-08-10

STUDIES ON A.C.OSCILLOPOLAROGRAM Ⅰ.TERMINAL POTENTIALS OF A.C.OSCILLOPOLAROGRAM IN SOLUTIONS CONTAINING ONLY SUPPORTING ELECTROLYTE

Bi Shuping, Ma Xinsheng, Gao Hong   

  1. Department of chemistry, Nanjing University
  • Received:1986-08-25 Revised:1987-02-21 Published:1987-08-10 Online:1987-08-10

摘要: 利用临界电流的概念,把Micka的复杂公式分解为不同电流密度下的简单公式来说明底液交流示波极谱图端点电位的原理。实验结果与理论基本相符。

Abstract: Micka's equation is reduced to some simple forms for terminal potentials, which explain the a.c. oscillopolarogram obtained at various current densities in solutions containing only supporting electrolyte. The theoretical conclusions are qualitatively confirmed through experimental work.