应用化学 ›› 1987, Vol. 0 ›› Issue (1): 40-43.

• 研究论文 • 上一篇    下一篇

1-丁烯齐聚反应——Ⅰ.六氟代戊二酮合镍/乙氧基二乙基铝的催化作用

高占先, 张爱丽, 于净, 周科衍   

  1. 大连工学院化工学院应用有机化学教研室
  • 收稿日期:1986-03-28 修回日期:1986-07-31 出版日期:1987-02-10 发布日期:1987-02-10

OLIGOMERIZATION REACTION OF 1-BUTENE Ⅰ.CATALYTIC BEHAVIOR 0F 1, 1, 1, 5, 5, 5-HEXAFLURO-2, 4-PEN-TADIONATO-NICKEL/DIETHYL ALUMINIUM ETHOXIDE

Gao Zhanxian, Zhang Aili, Yu Jing, Zhou Keyan   

  1. Dalian Institute of Technology
  • Received:1986-03-28 Revised:1986-07-31 Published:1987-02-10 Online:1987-02-10

摘要: 本文考察了1,1,1,5,5,5-六氟代戊二酮合镍/乙氧基二乙基铝催化1-丁烯的齐聚反应,证明它是1-丁烯线性齐聚反应的催化体系,同时也观察到了此体系对1-丁烯的异构化反应和加氢反应也有催化作用。

Abstract: In this paper, the oligomerization reaction of 1-butene has been studied using 1, 1, 1, 5, 5, 5 -haxafluro- 2, 4-pentadionato-nickel/diethyl aluminium ethoxide, (hfacac)2 Ni/Et2AlOEt, as catalyst. Results showed that (hfacac)2Ni/Et2AlOEt is an efficient catalyst for linear oligomerization of 1-butene and also cata1yzes isomerization and hydrogenation of 1-butene.