应用化学 ›› 1986, Vol. 0 ›› Issue (6): 73-75.

• 研究简报 • 上一篇    下一篇

硝酸铕与1,8-萘啶氮氧化物的荧光固态配合物的合成及性质

谭民裕, 甘新民, 唐宁, 翟应离   

  1. 兰州大学化学系
  • 收稿日期:1986-01-11 修回日期:1986-04-01 出版日期:1986-12-10 发布日期:1986-12-10
  • 通讯作者: 谭民裕

A FLUORESCENT SOLID CONIPLEX OF EUROPIUM NITRATE WITH 1,8-NAPHTHYRIDINE-N-OXIDE

Tan Minyu, Gan Xinmin, Tang Ning, Zhai Yingli   

  1. Department of Chemistry, Lanzhou University
  • Received:1986-01-11 Revised:1986-04-01 Published:1986-12-10 Online:1986-12-10

摘要: 1,8-萘啶氮氧化物用于金属离子配合物的合成至今尚未见报道。有资料介绍铕(Ⅲ)与芳香胺及其氮氧化物的配合物具有荧光,因而合成销(Ⅲ)与1,8-萘啶氮氧化物的配合物是有意义的。我们首次制得了这一新类型的荧光固态配合物。通过元素分析、红外光谱、紫外光谱、荧光光谱、摩尔电导及x光粉末衍射等测定,对新化合物进行了鉴定。

Abstract: The fluorescent solid complex of europium nitrate with 1, 8-naphthyridine-N-oxide (napyo) has been synthesized.The new complex has the composition Eu(napyo)2 (NO3)3 characterized by elemental analyses, infrared spectra, ultraviolet spectra, fluorescence spectra, molar conductance and x-ray powder diffraction measurements.