应用化学 ›› 1986, Vol. 0 ›› Issue (6): 48-53.

• 研究论文 • 上一篇    下一篇

Wesslau分布和Lansing-Kraemer分布在给定区间内的平均分子量

戴裕昆   

  1. 中国科学院长春应用化学研究所
  • 收稿日期:1985-08-16 出版日期:1986-12-10 发布日期:1986-12-10

THE AVERAGE MOLECULAR WEIGHT IN A GIVEN INTERVAL OF WESSLAU DISTRIBUTION AND LANSING-KRAEMER DISTRIBUTION

Dai Yukun   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1985-08-16 Published:1986-12-10 Online:1986-12-10

摘要: 由于Wesslau公式不够精确,用于计算分布较宽的正态GPC曲线将导致较大的误差。这一问题以往尚未为人们所觉察,本文推导出Wesslau分布及Lansins-Kraemer分布在给定区间内M的计算公式,不但可提高函数法计算M的准确度,而且对分布曲线的性质得出了一些新的结论。还指出了提高GPC法测定宽分布试样M准确度的途径。

Abstract: A formula for calculating M in a given interval of Wesslau distribution and Lansing-Kraemer distribution has been derived. It is impossible that the molecular weight of any polymer will distribute over the whole range of 0-∞, hencc a GPC curve always has two boundaries. Therefore a GPC curve should be treated as a normal distribution curve wih its side tails cut out. This paper has shown that three parame-ters (M0, β and UR ) are necessary for characterizing a normal GPC curve.The precision of M calculated from GPC curve by Wesslau function is discussed.