中华医学超声杂志

应用化学 ›› 1986, Vol. 0 ›› Issue (3): 35-39.

• 研究论文 • 上一篇    下一篇

醋酸乙烯与活性聚丁二烯基锂反应机理的探讨

申长江, 金关泰   

  1. 北京化工学院高分子系
  • 收稿日期:1985-03-09 修回日期:1985-05-10 出版日期:1986-06-10 发布日期:1986-06-10
  • 基金资助:
    中国科学院科学基金

ON THE MECHANISM OF THE REACTION BETWEEN VINYL ACETATE AND POLYBUTADIENYL-LITHIUM

Shen Changjiang, Jin Guantai   

  1. Beijing Institute of Chemical Technology
  • Received:1985-03-09 Revised:1985-05-10 Published:1986-06-10 Online:1986-06-10

PDF

374

摘要： 以萘锂为引发剂,抽余油为溶剂,探讨了醋酸乙烯与活性聚丁二烯基锂之间的反应机理。研究结果表明,醋酸乙烯加至活性聚丁二烯溶液中后,主要发生了偶联反应。同时,还向高分子链中引入了羟基。

Abstract: The mechanism of the reaction between acetate and polybutadienyl-lithium was inqui-red by using naphthalenelithium as initiator in extracted naphtha solution. It was found that a coupling reaction occurs after vinyl acetate and polybutadinyl lithium have been brou-ght together in an evacuated vessel acompanyied by a simultaneous introduce of hydroxyl groups into the polymer chain。

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