应用化学 ›› 1985, Vol. 0 ›› Issue (1): 70-73.

• 研究简报 • 上一篇    下一篇

硼化合物的研究Ⅹ。B10H102-、B10H122-及B3H8-双二茂铁季铵盐及环状二茂铁季铵盐的合成

张国敏, 祝虹, 丁强   

  1. 武汉大学化学系
  • 收稿日期:1984-05-07 修回日期:1984-10-04 出版日期:1985-03-10 发布日期:1985-03-10

STUDIES ON BORANE COMPOUNDS Ⅹ.SOME REACTIONS OF B10H102-,B12H122- AND B3H8= WITH (C5H5FeC5H4CH2NMe2Cl2)2R Fe(C5H4CH2NMe2Cl)2R

Zhang Guomin, Zhu Hong, Ding Qiang   

  1. Department of Chemistry, Wuhan University, wuhan
  • Received:1984-05-07 Revised:1984-10-04 Published:1985-03-10 Online:1985-03-10

摘要: 众所周知,二茂铁类和硼氢类化合物都具有特殊的化学结构,并且有可能作为高能材料得到应用。作者通过B10H102-、B12H122-及B3H8-与(N,N-二甲基胺甲基)二茂铁和1,1'-双(N,N-二甲基胺甲基)二茂铁卤化铵反应,曾合成了一系列新的化合物并研究了它们的反应性能和晶体结构[1-4]

Abstract: This paper deals with the reactions of the polyhedral boranes BHn3=(n:10 or 12) with (C3H5FeC5H4CH2NMe2Cl)2 R and Fe(C5H4CH2NMe2Cl)2R(R: -(CH2)4-, -CH2C≡CCH2-). The products were characterised by elemental analysis and IR spectroscopy.Melting points of the compounds were determined by differential thermal analysis.