应用化学 ›› 2010, Vol. 27 ›› Issue (01): 74-77.

• 研究论文 • 上一篇    下一篇

Sr2+-TiO2薄膜的制备及超亲水性

申树芳,刘秀芹,徐承天*,陈邦林   

  1. (华东师范大学 化学系 上海 200062)
  • 收稿日期:2008-12-25 修回日期:2009-07-09 出版日期:2010-01-10 发布日期:2010-01-10
  • 通讯作者: 徐承天,男,副教授; E-mail:ctxu@chem.ecnu.edu.cn; 研究方向:胶体与界面化学
  • 基金资助:
    “九七三”专项基金(2006CB932503)资助项目

Preparation and Superhydrophilicity of Sr2+ Doped TiO2 Films

SHEN Shu-Fang, LIU Xiu-Qin, XU Cheng-Tian*, CHEN Bang-Lin   

  1. (Department of Chemistry,East China Normal University,Shanghai 200062)
  • Received:2008-12-25 Revised:2009-07-09 Published:2010-01-10 Online:2010-01-10

摘要:

以钛酸丁酯作为前驱物,采用溶胶-凝胶法及浸渍-提拉法在载玻片上制备SrO-TiO2薄膜。通过X射线衍射和红外光谱等测试技术表征了SrO-TiO2粉末的结构,用紫外可见分光光度计测定薄膜的透光率,用接触角测试仪测定水与薄膜的接触角。结果表明,掺杂适量Sr2+后,SrO-TiO2粉末中TiO2晶粒的尺寸变小,SrO-TiO2薄膜表面吸附的羟基含量增多且稳定,可提高TiO2薄膜的超亲水性。经紫外光照1h或自然光照5h后,掺杂Sr2+(摩尔分数))为1.0%的SrO-TiO2薄膜与水的接触角接近于0°,表现出良好的亲水性。

关键词: TiO2膜,超亲水性,Sr2 掺杂,接触角

Abstract:

With tetrabutyltitanate as a precursor, the Sr-TiO2 films coated on the sheet glass substrates were prepared respectively by sol-gel method and dip-coating technique. The structure of SrO-TiO2 powder was characterized by XRD and IR. The transmission rate of the films were measured on the Uv-Vis spectrophotometer. The contact angle between the film and water was also mesued with the contact angle mesuring instrument. The results obtained are as follows: the grain size of TiO2 in Sr-TiO2 powder become smaller when a proper amount of Sr2+ was doped. The hydroxyl content on the thin film and its stability have been increased, which are beneficial to the superhydrophilicity of the film. Under the irradiation of ultraviolet light for an hour or natural light for five hours, the contect angle between the water and Sr-TiO2 thin film with 1.0%(mole percentage) of Sr2+ doping amount was close to 0°, the water can easily fully roll out on the film surface, the thin film shows good hydrophilicity.

 

Key words: TiO2film, superhydrophilicity, Sr2 doping, contact angle

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