有机阳离子修饰的Strandberg型钼磷酸盐的合成、催化性能

刘昭宇^b, 朱浩天^a, 卢明达^a, 李晓辉^a, 安悦^a*,^*, 张澜萃^a*,^*

Synthesis and Catalytic Activity of a Strandberg-type Molybdophosphate Modified by Organic Cations

LIU Zhaoyu^b, ZHU Haotian^a, LU Mingda^a, LI Xiaohui^a, AN Yue^a,^*, ZHANG Lancui^a,^*

图6 合成环己酮缩乙二醇反应的影响因素
Fig.6 Effect of reaction parameters on the yield of cyclohexanone ethylene ketal
Reaction conditions: A .the molar ratio of cyclohexanone to glycol was 1∶1.41.0 mol of cyclohexanone, reaction time 2.5 h; B .the molar ratio of the catalystbased on Mo to cyclohexanone was 1∶300, reaction time 2.5 h; C .the molar ratio of cyclohexanone to glycol was 1∶1.41.0 mol of cyclohexanone, the molar ratio of the catalystbased on Mo to cyclohexanone was 1∶300. water-carring agent:10 mL of cyclohexane; reaction temperature: 95100 ℃.