9,10-双-(对-(甲氧基二缩三乙二醇基)苯基乙炔基)蒽的合成、自组装及其光谱分析

金光日^a, 朱吉凯^a, 钟克利^b, 陈铁^a, 金龙一^a*,^*

Synthesis, Self-Assembly and Spectroscopic Analysis of 9,10-Bis((4-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)phenyl)ethynyl)anthracene

JIN Guangri^a, ZHU Jikai^a, ZHONG Keli^b, CHEN Tie^a, JIN Longyi^a,^*

Scheme 1 Synthetic route of the compound 1
Reagents and conditions:aTsCl,pyridine,CH 2 Cl 2 ,r.t.,12 h; b4-Iodophenol,K 2 CO 3 ,CH 3 CN,refluxing,24 h; cTrimethylsilylacetylene,CuI,PdPPh 3 4 ,toluene,NEt 3 ,refluxing,48 h; d10%KOH,CH 3 OH,THF,refluxing,2 h; eCuI,PdPPh 3 4 ,THF,NEt 3 ,refluxing,48 h