Preparation of Large-size Graphene Oxide Films Based on Iron(Ⅲ) Chloride Catalysis

doi:10.11944/j.issn.1000-0518.2018.02.170083

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (2): 232-238.DOI: 10.11944/j.issn.1000-0518.2018.02.170083

• Full Papers • Previous Articles Next Articles

Preparation of Large-size Graphene Oxide Films Based on Iron(Ⅲ) Chloride Catalysis

LI Zhanguo^a,FAN Sida^a^b,ZHANG Liang^b,ZHANG Peipei^a^b,SUN Lijing^b,YIN Li^b,ZHANG Jidong^c,WANG Lijuan^b^*()

^aSchool of Electro-Optical Engineering,Changchun University of Science and Technology,Changchun 130022,China
^bSchool of Chemical Engineering,Changchun University of Technology,Changchun 130012,China
^cState Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China

Received:2017-03-24 Accepted:2017-06-26 Published:2018-02-01 Online:2018-01-29
Contact: WANG Lijuan
Supported by:
Supported by the National Natural Science Foundation of China(No.21403016), the Scientific Research Foundation of Education Department of Jilin Province(No.2016326, No.JJKH20170556KJ), the Key Program for Science and Technology Development of Jilin Province of China(No.20170204014SF)

Abstract

Abstract:

In order to obtain large-area graphene oxide(L-GO) films, a series of FeCl₃-catalyzed L-GO films are prepared. The surface morphology and structure of L-GO films synthesized with various temperatures and times are studied by atomic force microscope(AFM), polarizing microscope(POM), Fourier transform infrared spectrometer(FTIR), and X-ray diffraction(XRD). The sheet domain area of FeCl₃-catalyzed L-GO films is 10 μm×10 μm, which increases about four times in contrast to that of GO films prepared without catalyst. By further analysis of FTIR and XRD, the formation of L-GO domains can be attributed to the new connections of the hydroxyl, carboxyl, and carbonyl groups in graphene oxide under FeCl₃ catalysis. Thus, a formation model of FeCl₃-catalyzed L-GO films is proposed, which provides a new way for the preparation of large area graphene oxide films.

Key words: iron chloride, catalyst, graphene oxide sheet, large-size thin film, surface morphology, Fourier transform infrared spectroscopy

LI Zhanguo, FAN Sida, ZHANG Liang, ZHANG Peipei, SUN Lijing, YIN Li, ZHANG Jidong, WANG Lijuan. Preparation of Large-size Graphene Oxide Films Based on Iron(Ⅲ) Chloride Catalysis[J]. Chinese Journal of Applied Chemistry, 2018, 35(2): 232-238.

References

[1]	Kim W K,Jung Y M,Cho J H,et al.Radio-frequency Characteristics of Graphene Oxide[J]. Appl Phys Lett,2010,97(19):193103.
[2]	Rogers G W,Liu J Z.Monolayer Graphene Oxide as a Building Block for Artificial Muscles[J]. Appl Phys Lett,2013,102(2):021903.
[3]	Liu J,Galpaya D,Notarianni M,et al.Graphene-based Thin Film Supercapacitor with Graphene Oxide as Dielectric Spacer[J]. Appl Phys Lett,2013,103(6):063108.
[4]	Hong S K,Eun Kim J,Sang O K,et al.Analysis on Switching Mechanism of Graphene Oxide Resistive Memory Device[J]. J Appl Phys,2011,110(4):044506.
[5]	Ni Z H,Wang H M,Kasim J,et al.Graphene Thickness Determination Using Reflection and Contrast Spectroscopy[J]. Nano Lett,2007,7(9):2758-2763.
[6]	Bolotin K I,Sikes K J,Jiang Z,et al.Ultrahigh Electron Mobility in Suspended Graphene[J]. Solid State Commun,2008,146(2008):351-355.
[7]	Novoselov K S,Jiang Z,Zhang Y,et al.Room-Temperature Quantum Hall Effect in Graphene[J]. Science,2007,315(9):1379.
[8]	Lee Y B,Ahn J H.Graphene-based Transparent Conductive Films[J]. Nano Brief Rep Rev,2013,8(3):1330001.
[9]	Mao S,Pu H,Chen J.Graphene Oxide andIts Reduction:Modeling and Experimental Progress[J]. Rsc Adv,2012,24(19):10560-10564
[10]	Balandin A A,Ghosh S,Bao W,et al.Superior Thermal Conductivity of Single-layer Graphene[J]. Nano Lett,2008,8(3):902-907
[11]	Zheng Q B,Ip W H,Lin X Y,et al.Transparent Conductive Films Consisting of Ultralarge Graphene Sheets Produced by Langmuir-Blodgett Assembly[J]. ACS Nano,2011,5(7):6039-6051.
[12]	Zhao J,Pei S,Ren W,et al.Efficient Preparation of Large-area Graphene Oxide Sheets for Transparent Conductive Films[J]. ACS Nano,2010,4(9):5245-5252.
[13]	Jr W S H,Offeman R E. Preparation of Graphitic Oxide[J]. J Am Chem Soc,1958,80:1339
[14]	Hirata M,Gotou T,Horiuchi S,et al.Thin-film Particles of Graphite Oxide 1:High-yield Synthesis and Flexibility of the Particles[J]. Carbon,2004,42:2929-2937.
[15]	SONG Yang,TANG Xuesong,HOU Xiaomeng,et al.Advances of Iron(Ⅲ) ChIoride-Catalyzed Origanic Reactions[J]. Chinese J Org Chem,2013,33:76-89(in Chinese). 宋阳,唐雪松,侯晓萌,等. 三氯化铁催化的有机反应研究进展[J]. 有机化学,2013,33:76-89.
[16]	ZOU Fengjun,FAN Sida,XIE Qiang,et al.Effect of Doping Graphene Quantum Dots on the Performance of P3HT:PCBM Solar Cell[J]. Chinese J Lumin,2016,37(9):1082-1089(in Chinese). 邹凤君,范思大,谢强,等. 掺杂石墨烯量子点对P3HT:PCBM太阳能电池性能的影响[J]. 发光学报,2016,37(9):1082-1089.
[17]	Li M,Ni W,Kan B,et al.Graphene Quantum Dots as the Hole Transport Layer Material for High-performance Organic Solar Cells[J]. Phys Chem Chem Phys,2013,15:18973-18978.
[18]	YANG Yonghui,SUN Hongjuan,PENG Tongjiang,et al.Synthesis and Structural Characterization of Graphene-Based Membranes[J]. Acta Phys-Chim Sin,2010,26(11):2083-2090(in Chiese). 杨勇辉,孙红娟,彭同江,等. 石墨烯的氧化还原法制备及结构表征[J]. 无机化学学报,2010,26(11):2083-2090.
[19]	Paredes J I,Villarrodil S,Martínezalonso A,et al.Graphene Oxide Dispersions in Organic Solvents[J]. Langmuir,2008,24(19):10560-10564.
[20]	Bagani K,Bhattacharya A,Kaur J,et al.Anomalous Behaviour of Magnetic Coercivity in Graphene Oxide and Reduced Graphene Oxide[J]. J Appl Phys,2014,115(2):023902.
[21]	Lee D W,De L S V L,Seo J W,et al. The Structure of Graphite Oxide:Investigation of Its Surface Chemical Groups[J]. J Phys Chem B,2010,114(17):5723-5728.
[22]	Jeong H K,Lee Y P,Lahaye R J,et al.Evidence of Graphitic AB Stacking Order of Graphite Oxides[J]. J Am Chem Soc,2008,130(4):1362-1366.
[23]	Moraes A C M D,Andrade P F,Faria A F D,et al. Fabrication of Transparent and Ultraviolet Shielding Composite Films Based on Graphene Oxide and Cellulose Acetate[J]. Carbohydr Polym,2015,123:217-227.
[24]	Zhu Y,Murali S,Cai W,et al.Graphene and Graphene Oxide:Synthesis, Properties, and Applications[J]. Adv Mater,2010,22:3906-3924.

Preparation of Large-size Graphene Oxide Films Based on Iron(Ⅲ) Chloride Catalysis

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yi-Cheng ZHANG, Fei ZHA, Xiao-Hua TANG, Yue CHANG, Hai-Feng TIAN, Xiao-Jun GUO. Research Progress of Heterogeneous Catalytic Preparation of Organic Peroxides [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 769-788.
[2]	Yi-Chen YU, Yu-Chen ZHANG, Yao-Yuan ZHANG, Qin WU, Da-Xin SHI, Kang-Cheng CHEN, Han-Sheng LI. Research Progress of Bulk Metal Oxides for Non-oxidative Propane Dehydrogenation [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 789-805.
[3]	Bing LI, Jun-Hui LIU, Ya-Kun SONG, Xiang LI, Xu-Ming GUO, Jian XIONG. Recent Advances in Application of Metal-Organic Frameworks for Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane [J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 329-340.
[4]	Lu-Fei WANG, Meng-Meng ZHEN, Bo-Xiong SHEN. Research Progress of Controlling Lithium-Sulfur Batteries by Electrocatalysts under Lean Electrolyte Conditions [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 188-209.
[5]	Rong CAO, Jie-Zhen XIA, Man-Hua LIAO, Lu-Chao ZHAO, Chen ZHAO, Qi WU. Theoretical Research Progress of Single Atom Catalysts in Electrochemical Synthesis of Ammonia [J]. Chinese Journal of Applied Chemistry, 2023, 40(1): 9-23.
[6]	Dan ZHANG, Run-Mei SHANG, Zhen-Tao ZHAO, Jun-Hua LI, Jin-Juan XING. Selective Oxidation of Methanol to Dimethoxymethane over V/Ce⁃Al₂O₃ Catalysts [J]. Chinese Journal of Applied Chemistry, 2022, 39(9): 1429-1436.
[7]	Xian WANG, Xiao-Long YANG, Rong-Peng MA, Chang-Peng LIU, Jun-Jie GE, Wei XING. Atomic Dispersion Ir‑N‑C Catalysts for Anode Anti‑poisoning Electrolysis in Fuel Cell [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1202-1208.
[8]	Ye LIU, Shao-Bo GUO, Yan-Li LIANG, Hong-Guang GE, Jian-Qi MA, Zhi-Feng LIU, Bo LIU. Preparation and Catalytic Performance of Core‑Shell CuFe₂O₄@NH₂@Pt Nanocomposites [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1237-1245.
[9]	Quan-Xing ZHENG, Qiao-Ling LI, Ke ZHANG, Pei-Chen ZHOU, Jiang-Sheng LIU, Xiu-Cai LIU, Chao-Zhang HUANG, Bin LI, Han-Chun XU, Hong-Qiao LAN, Jia-Zeng LIU, Peng-Fei MA, Wei XIE, Xiao-Dong YI. Pyrolysis Process of Plant Fibers [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1073-1082.
[10]	Chao ZHANG. Research Prospect of Single Atom Catalysts Towards Electrocatalytic Reduction of Carbon Dioxide [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 871-887.
[11]	Shi-Shuai LI, Jia-Qi LIU, Jia-Yi WANG, Jiang-Feng YANG. Research Progress on Synthesis of Hierarchical Beta Zeolites [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 912-926.
[12]	Yan WANG, Shu-Cong ZHANG, Xing-Kun WANG, Zhi-Cheng LIU, Huan-Lei WANG, Ming-Hua HUANG. Research Progress on Transition Metal⁃Based Catalysts for Hydrogen Evolution Reaction via Seawater Electrolysis [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 927-940.
[13]	Feng LI, Shi-Yu LU, Yu ZHANG, Li-Jun GUO, Xue ZHAI, Cui-Qin LI. Catalytic Properties of Silylated⁃Salicylaldimine Transition Metal Complexes Functionalized Nano⁃silica Catalysts in Ethylene Oligomerization [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 949-959.
[14]	Wei-Jin CAO, Lu BAI, Lan-Lan WU, Jing-De LI, Shu-Yan SONG. Multi⁃Shell Hollow Nickel⁃Cobalt Bimetallic Phosphide Nanospheres for Highly Efficient Oxygen Evolution Reaction [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 666-672.
[15]	Xue WANG, Yi-Bo WANG, Xian WANG, Jian-Bing ZHU, Jun-Jie GE, Chang-Peng LIU, Wei XING. Research Progress of Mechanism of Acidic Oxygen Evolution Reaction and Development of Ir⁃based Catalysts [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 616-628.