Electrochemical Detection of Antioxidants in Cosmetic Samples Using Mesoporous Silica Film and Confined Micelles

doi:10.11944/j.issn.1000-0518.2017.11.170251

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (11): 1307-1313.DOI: 10.11944/j.issn.1000-0518.2017.11.170251

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Electrochemical Detection of Antioxidants in Cosmetic Samples Using Mesoporous Silica Film and Confined Micelles

DING Hao,YAN Fei,ZHENG Wenjing,GUO Weiliang,SU Bin()

Institute of Analytical Chemistry,Department of Chemistry,Zhejiang University,Hangzhou 310058,China

Received:2017-07-18 Accepted:2017-08-30 Published:2017-11-08 Online:2017-11-08
Contact: SU Bin
Supported by:
Supported by the National Natural Science Foundation of China(No.21335001, No.21575126), the Natural Science Foundation of Zhejiang Province(No.LR14B050001)

Abstract

Abstract:

This work presents a novel approach for the electrochemical determination of butylated hydroxyanisole(BHA) and tert-butylhydroquinone(TBHQ) in real cosmetic samples using the indium tin oxide(ITO) electrodes modified with vertically aligned mesoporous silica channels retaining micelles of cetyltrimethylammonium bromide(CTAB). The ultra-small pore size of the channels, namely 2.3 nm in diameter, rendered the size screening capability of the electrode. Meanwhile, the hydrocarbon tails of CTAB provided a hydrophobic microenvironment, which enabled the rapid extraction and preconcentration of lipophilic organic analytes from sample solutions. An excellent analytical sensitivity, a wide dynamic range and a low limit of detection were obtained for both antioxidants under optimized conditions. Recovery values between 96.4% and 104% indicate the practical usefulness of the proposed sensor.

Key words: electrochemical sensor, mesoporous silica film, antioxidants, micelles, cosmetic

DING Hao, YAN Fei, ZHENG Wenjing, GUO Weiliang, SU Bin. Electrochemical Detection of Antioxidants in Cosmetic Samples Using Mesoporous Silica Film and Confined Micelles[J]. Chinese Journal of Applied Chemistry, 2017, 34(11): 1307-1313.

References

[1]	Ziyatdinova G,Os'kina K,Ziganshina E,et al. Simultaneous Determination of TBHQ and BHA on a MWNT-Brij® 35 Modified Electrode in Micellar Media[J]. Anal Methods,2015,7(19):8344-8351.
[2]	Guan Y,Chu Q,Fu L,et al.Determination of Antioxidants in Cosmetics by Micellar Electrokinetic Capillary Chromatography with Electrochemical Detection[J]. J Chromatogr A,2005,1074(1/2):201-204.
[3]	Wang J Y,Wu H L,Chen Y,et al.Quantitative Determination of Butylated Hydroxyanisole and n-Propyl Gallate in Cosmetics Using Three-Dimensional Fluorescence Coupled with Second-Order Calibration[J]. Talanta,2013,116:347-353.
[4]	Capitan-Vallvey L F,Valencia M C,Nicolas E A. Monoparameter Sensors for the Determination of the Antioxidants Butylated Hydroxyanisole and n-Propyl Gallate in Foods and Cosmetics by Flow Injection Spectrophotometry[J]. Analyst,2001,126(6):897-902.
[5]	Capitan-Vallvey L F,Valencia M C,Nicolas E A. Simple Resolution of Butylated Hydroxyanisole and n-Propyl Gallate in Fatty Foods and Cosmetics Samples by Flow-Injection Solid-Phase Spectrophotometry[J]. J Food Sci,2003,68(5):1595-1599.
[6]	Cacho J I,Campillo N,Viñas P,et al.Determination of Synthetic Phenolic Antioxidants in Edible Oils Using Microvial Insert Large Volume Injection Gas-Chromatography[J]. Food Chem,2016,200:249-254.
[7]	Chen M,Hu X J,Tai Z G,et al.Determination of Four Synthetic Phenolic Antioxidants in Edible Oils by High-Performance Liquid Chromatography with Cloud Point Extraction Using Tergitol TMN-6[J]. Food Anal Methods,2013,6(1):28-35.
[8]	Biparva P,Ehsani M,Hadjmohammadi M R.Dispersive Liquid-Liquid Microextraction Using Extraction Solvents Lighter than Water Combined with High Performance Liquid Chromatography for Determination of Synthetic Antioxidants in Fruit Juice Samples[J]. J Food Compos Anal,2012,27(1):87-94.
[9]	Touati R,Santos S A O,Rocha S M,et al. The Potential of Cork from Quercus Suber L. Grown in Algeria as a Source of Bioactive Lipophilic and Phenolic Compounds[J]. Ind Crop Prod,2015,76:936-945.
[10]	Rodil R,Quintana J B,Basaglia G,et al.Determination of Synthetic Phenolic Antioxidants and Their Metabolites in Water Samples by Downscaled Solid-Phase Extraction, Silylation and gas Chromatography-Mass Spectrometry[J]. J Chromatogr A,2010,1217(41):6428-6435.
[11]	Wang P,Han C,Zhou F,et al.Electrochemical Determination of Tert-Butylhydroquinone and Butylated Hydroxyanisole at Choline Functionalized Film Supported Graphene Interface[J]. Sens Actuators B,2016,224:885-891.
[12]	Sousa Carvalho R M,Yotsumoto Neto S,Carvalho Silva F,et al. A Sensitive Sensor Based on CuTSPc and Reduced Graphene Oxide for Simultaneous Determination of the BHA and TBHQ Antioxidants in Biodiesel Samples[J]. Electroanalysis,2016,28(12):2930-2938.
[13]	Lin X,Ni Y,Kokot S.Glassy Carbon Electrodes Modified with Gold Nanoparticles for the Simultaneous Determination of Three Food Antioxidants[J]. Anal Chim Acta,2013,765:54-62.
[14]	Niu X,Yang W,Guo H,et al.A Novel Strategy for the Detection of tert-Butylhydroquinone Based on Graphene Quantum Dots and Silver Nanoparticle Modified Glass Carbon Electrode[J]. Can J Chem,2015,93(6):648-654.
[15]	Roushani M,Sarabaegi M.Electrochemical Detection of Butylated Hydroxyanisole Based on Glassy Carbon Electrode Modified by Iridium Oxide Nanoparticles[J]. J Electroanal Chem,2014,717:147-152.
[16]	Caramit R P,Antunes Araújo A S,Fogliatto D K,et al. Carbon-Nanotube-Modified Screen-Printed Electrodes, a Cationic Surfactant, and a Peak Deconvolution Procedure:Alternatives to Provide Satisfactory Simultaneous Determination of Three Synthetic Antioxidants in Complex Samples[J]. Anal Methods,2015,7(9):3764-3771.
[17]	Caramit R P,de Freitas Andrade A G,Gomes de Souza J B,et al. A New Voltammetric Method for the Simultaneous Determination of the Antioxidants TBHQ and BHA in Biodiesel Using Multi-Walled Carbon Nanotube Screen-Printed Electrodes[J]. Fuel,2013,105:306-313.
[18]	Gan T,Zhao A X,Wang S H,et al.Hierarchical Triple-Shelled Porous Hollow Zinc Oxide Spheres Wrapped in Graphene Oxide as Efficient Sensor Material for Simultaneous Electrochemical Determination of Synthetic Antioxidants in Vegetable Oil[J]. Sens Actuators B,2016,235:707-716.
[19]	Cui M,Liu S,Lian W J,et al.A Molecularly-Imprinted Electrochemical Sensor Based on a Graphene-Prussian Blue Composite-Modified Glassy Carbon Electrode for the Detection of Butylated Hydroxyanisole in Foodstuffs[J]. Analyst,2013,138(20):5949-5955.
[20]	dos Santos Moretti E,de Oliveira F M,Scheel G L,et al. Synthesis of Surface Molecularly Imprinted Poly(methacrylic acid-hemin) on Carbon Nanotubes for the Voltammetric Simultaneous Determination of Antioxidants from Lipid Matrices and Biodiesel[J]. Electrochim Acta,2016,212:322-332.
[21]	Yue X,Song W,Zhu W,et al.In Situ Surface Electrochemical Co-Reduction Route Towards Controllable Construction of AuNPs/ERGO Electrochemical Sensing Platform for Simultaneous Determination of BHA and TBHQ[J]. Electrochim Acta,2015,182:847-855.
[22]	Rao H,Wang X,Du X,et al.Mini Review: Electroanalytical Sensors of Mesoporous Silica Materials[J]. Anal Lett,2013,46(18):2789-2812.
[23]	Serrano M B,Despas C,Herzog G,et al.Mesoporous Silica Thin Films for Molecular Sieving and Electrode Surface Protection Against Biofouling[J]. Electrochem Commun,2015,52:34-36.
[24]	Walcarius A,Mercier L.Mesoporous Organosilica Adsorbents:Nanoengineered Materials for Removal of Organic and Inorganic Pollutants[J]. J Mater Chem,2010,20(22):4478.
[25]	Sun Q,Yan F,Yao L,et al.Anti-Biofouling Isoporous Silica-Micelle Membrane Enabling Drug Detection in Human Whole Blood[J]. Anal Chem,2016,88(17):8364-8368.
[26]	Yao L,Yan F,Su B.Highly Ordered Surfactant Micelles Function as the Extraction Matrix for Direct Electrochemical Detection of Halonitrobenzenes at the ppb Level[J]. Analyst,2016,141(7):2303-2307.
[27]	Yan F,Su B,Tailoring Molecular Permeability of Nanochannel-Micelle Membranes for Electrochemical Analysis of Antioxidants in Fruit Juices without Sample Treatment[J]. Anal Chem,2016,88(22):11001-11006.
[28]	Zheng W,Yan F,Su B.Electrochemical Determination of Chloramphenicol in Milk and Honey Using Vertically Ordered Silica Mesochannels and Surfactant Micelles as the Extraction and Anti-Fouling Element[J]. J Electroanal Chem,2016,781:383-388.
[29]	Teng Z,Zheng G,Dou Y,et al.Highly Ordered Mesoporous Silica Films with Perpendicular Mesochannels by a Simple Stober-Solution Growth Approach[J]. Angew Chem Int Ed,2012,51(9):2173-2177.
[30]	Etienne M,Quach A,Grosso D,et al.Molecular Transport into Mesostructured Silica Thin Films:Electrochemical Monitoring and Comparison Between p6m, P63/mmc, and Pm3n Structures[J]. Chem Mater,2007,19(4):844-856.
[31]	Yan F,Lin X,Su B.Vertically Ordered Silica Mesochannel Films:Electrochemistry and Analytical Applications[J]. Analyst,2016,141(12):3482-3495.

Electrochemical Detection of Antioxidants in Cosmetic Samples Using Mesoporous Silica Film and Confined Micelles

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