应用化学

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发光碳量子点的合成、性质和应用

张川洲1,谭辉1,毛燕1,2,李刚1,韩冬雪2*,牛利2   

  1. (1.吉林省产品质量监督检验院 长春 130022;2.中国科学院长春应用化学研究所 长春 130022)
  • 收稿日期:2012-10-15 修回日期:2012-11-02 出版日期:2013-04-10 发布日期:2013-04-10
  • 通讯作者: 韩冬雪,副研究员; Tel:0431-85262425; Fax:0431-85262800; E-mail:dxhan@ciac.jl.cn; 研究方向:纳米结构材料和生物传感
  • 基金资助:
    国家自然科学基金(21205112)吉林省科技发展计划项目(201215091)资助

Synthesis and Properties of Luminescent Carbon Dots and Its Applications

ZHANG Chuanzhou1, TAN Hui1, MAO Yan1,2, LI Gang1, HAN Dongxue2*, NIU Li2   

  1. (1.Jilin Product Quality Supervision Test Institute,Changchun 130022,China;
    2.Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China)
  • Received:2012-10-15 Revised:2012-11-02 Published:2013-04-10 Online:2013-04-10

摘要: 基于碳量子点具有良好的水溶性、化学惰性、低毒性、易于功能化和抗光漂白性等优异性能,碳量子点和其它的碳纳米材料(如富勒烯、碳纳米管和石墨烯等)同样引起了研究者广泛的关注。 碳量子点可以通过很多较为廉价的一步法进行大规模的制备,包括化学氧化法、超声法、微波法和激光烧蚀法等。 本文主要介绍了不同碳量子点的合成方法,以及依赖于碳量子点尺寸和波长等性质的发光性能,并且讨论了碳量子点在生物成像、光催化、能量转换/储存、光电子、光限幅和传感器等方面的应用。

关键词: 碳量子点, 荧光, 量子点, 纳米粒子

Abstract: Similar to other carbon nano-materials, such as fullerenes, carbon nanotubes and graphene, carbon dots(C-dots) have inspired intensive research attention according to their superior solubility in water, chemical inertness, low toxicity, easy functionalization and resistance to photobleaching. C-dots can be produced inexpensively through lots of one-tep approaches on a large scale such as simple chemical oxidation reactions, ultrasonic treatment, microwave method and laser ablation strategy, etc. In this review, we mainly introduced different synthesis approaches of C-dots, size- and wavelength-dependent luminescence emission property, etc. Furthermore, applications of C-dots in photocatalysis, energy conversion/storage, bioimaging, optoelectronics, optical limiting, sensors, etc. were also discussed.

Key words: carbon dots, fluorescence, quantum dots, nanoparticles

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